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541.64:542.952
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1 , 450074, . , . , 32; . (347) 2736778, e-mail: ksa.85@mail.ru , 2 - , 3 ,
4 450054, . , . , 71; . (347) 2356166, 2353815, e-mail: islamova@anrb.ru
S. A. Kazaryants1, S. R. Ivanova1, Sh. M. Salikhov2, I. B. Abdrakhmanov2, R. M. Islamova2
3,1-benzoxazine as new additive for controlled radical polymerization of methyl methacrylate
1 Bashkir State University 32, Zaki Validi Str, 450074, Ufa, Russia; ph. (347) 2736778, e-mail: ksa.85@mail.ru 2Institute of Organic Chemistry of Ufa Scientific Center of Russian Academy of Sciences 71, Oktyabrya Pr, Ufa, 450054, Russia; ph. (347) 2356166, 2353815, e-mail: islamova@anrb.ru
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The synthesis of new complex compound on the base of 2-phenylspiro[3,1-benzoxazine-4,1'-cyclo-pentane] and cuprous chloride (II) was realized. Features of polymerization of methyl methacrylate over a copper complex were studied. That was shown, the process run as living polymerization as well as general free radical polymerization.
Key words: benzoxazine; methyl methacrylate; atom transfer radical polymerization (ATRP).
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